Tetrahedron Letters p. 555 - 558 (1988)
Update date:2022-08-02
Topics:
Shono, Tatsuya
Nozoe, Tetsuo
Maekawa, Hirofumi
Kashimura, Shigenori
Cycloheptatriene (CHT) has been directly transformed to 7-methoxycycloheptatriene (7-MCHT), an equivalent compound to a tropolium salt, by the anodic oxidation of CHT in methanol.The further anodic oxidation of 3-MCHT prepared from 7-MCHT has been found to be an effective method of synthesis of tropone and tropolone.
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(1953)Doi:10.1021/ja00834a020
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(2019)Doi:10.1248/cpb.58.191
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(2013)
