Organic Letters p. 2102 - 2105 (2016)
Update date:2022-08-04
Topics:
Wang, Qiang
Li, Xingwei
Nitrosobenzenes have been used as a convenient aminating reagent for the efficient synthesis of 1H-indazoles via rhodium and copper catalyzed C-H activation and C-N/N-N coupling. The reaction occurred under redox-neutral conditions with high efficiency and functional group tolerance. Moreover, a rhodacyclic imidate complex has been identified as a key intermediate.
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