Journal of the Chemical Society, Dalton Transactions p. 515 - 520 (1988)
Update date:2022-08-05
Topics:
Henderson, Richard A.
The mechanisms of the reactions of acid (HCl or HBr) or the nucleophiles CO, MeCN, or PhCN with trans-a molecule of solvent or the nucleophile.Subsequent loss of dinitrogen and phosphine chelate ring closure (and for the solvent route, displacement of the co-ordinated solvent by a molecule of the nucleophile) yields the product trans-a much slower pathway involving initial rate-limiting dissociation of dinitrogen.The reasons for the change in substitution mechanism between the mononuclear and binuclear complexes are discussed.
Dongying J&M Chemical Co., Ltd,
Contact:546-8551108
Address:Room 1219, Zisheng Mansion, Zibo Road, Dongying, Shandong, China
Contact:+86-571-86025531 / 86024803
Address:1218-24 Guangyin Mansion,42 Fengqi East Road
Contact:+86-515-88356562
Address:No.2, West Daqing Road, Yancheng, Jiangsu, China
Shandong Xinke Petrochemical Co., Ltd.
Contact:+86-546-7277016
Address:Gudao Industrial Park, Hekou District, Dongying, Shandong Province, China
website:http://www.synchemie.com/
Contact:+86-574-87642758
Address:Room 901, Yinyi Bund Building， 132 Renmin Road
Doi:10.1139/v03-211
(2004)Doi:10.1016/0040-4020(75)85105-2
(1975)Doi:10.1021/ja01570a051
(1957)Doi:10.1016/S0020-1693(02)01292-6
(2003)Doi:10.1021/ja00857a021
(1975)Doi:10.1021/jo01144a014
(1951)
