Angewandte Chemie - International Edition p. 2036 - 2040 (2003)
Update date:2022-08-02
Topics:
Kubo, Yohei
Yamamoto, Masashi
Ikeda, Masato
Takeuchi, Masayuki
Shinkai, Seiji
Yamaguchi, Shigehiro
Tamao, Kohei
Perturbation in the energy-transfer pathway and of the π conjugation between the chromophores in a triarylborane-porphyrin conjugate on coordination of a fluoride ion to the boron center is assumed to account for the observation of the three emission bands (at 356, 670, and 692 nm). The system also displays a colorimetric (purple to green, see picture, and red to bluish emission) response to fluoride ions.
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