A Direct Relationship between Nucleophilicity and Basicity in SN2 Reactions of Fluorenyl Anions with Benzyl Chloride in Dimethyl Sulfoxide Solution

DOI: 10.1021/jo01304a035

Source and publish data:

Journal of Organic Chemistry p. 3314 - 3320 (1980)

Update date:2022-07-29

Topics:

Authors:

Bordwell, Frederick G.

Hughes, David L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01304a035

The rates of reactions for nine 9-substituted fluorenyl anions, 9-G-Fl^- (G=CN, CO2Me, PhSO2, PhS, Ph, PhO, PhCH2, Me, t-Bu), reacting with benzyl chloride in Me2SO solution have been measured.For 9-CN-Fl^- the rates increased with sol

Full text of DOI:10.1021/jo01304a035

Products guided by the article

Product name:9-Benzyl-9-phenylsulfonylfluoren

Cas No:57643-30-8

R&D Labs maybe for 57643-30-8

Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
SHAANXI TOP PHARM CHEMICAL CO.LTD

Contact:+86-029-85733403

Address:No.108 ,west sector,south er huan,xi'an,china
MINS GROUP CO.,LIMITED

Contact:18669908765

Address:Zibo City, Shandong Province, P.R.China
Jiangxi Biochem Co.,Ltd

Contact:86-791-86629460

Address:1-6F, 118 Xinzhou road, Nanchang, Jiangxi, China
Chengda Pharmaceuticals Co., Ltd.

Contact:+86-573-84601188

Address:hengshan Road 5# in Jiashan, zhejiang

Relevant to this article

Doi:10.1016/0040-4020(75)87052-9
(1975)
Doi:10.1021/ja01207a603
(1946)
Azulenylcarbene and Naphthylcarbene Isomerizations. Falling Solid Flash Vacuum Pyrolysis

Doi:10.1021/acs.joc.5b00412
(2015)
Reactions of chlorocarbonyl isocyanate with 5-aminopyrazoles and active methylene nitriles: A novel synthesis of pyrazolo[1,5-a]-1,3,5-triazines and barbiturates

Doi:10.1081/SCC-100106205
(2001)
Accessing the Rare Diazacyclobutene Motif

Doi:10.1021/acs.orglett.8b03590
(2018)
Transformations of penicillins: reactions of penam S-oxides with N-chloro-N-sodiocarbamates.

Doi:10.1039/P19770001943
(1977)

Article Doi