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Electrochemical studies on organometallic compounds XXXVI. New aspects of the electroreduction of (Ph2Sb)2O, (Ph2Sb)2, Ph2Sb(nBu), and Ph3Sb

DOI: 10.1016/0022-328X(90)87006-Y

Source and publish data:

Journal of Organometallic Chemistry p. 85 - 90 (1990)

Update date:2022-08-05

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Authors:

Mourad, Y.Mourad, Y.

Mugnier, Y.Mugnier, Y.

Breunig, H.J.Breunig, H.J.

Ates, M.Ates, M.

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Article abstract of DOI:10.1016/0022-328X(90)87006-Y

Electroreduction of (Ph2Sb)2O (1) in THF gives Ph2Sb-, which can also be obtained by uptake of two electrons on (Ph2Sb)2 (2).Ph2Sb- reacts with the supporting salt (nBu4NPF6) to yield tributylamine and Ph2Sb(nBu) (3).The electroreduction of 3 and Ph3Sb (4) gives also the anion Ph2Sb-.There is a considerable influence of the electrode surface on the redox properties of 1-4.Mechanistic aspects are discussed.

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Full text of DOI:10.1016/0022-328X(90)87006-Y

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Product name:Ph2Sb(n-Bu)

Cas No:58284-59-6

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