Bulletin of the Chemical Society of Japan p. 709 - 719 (2003)
Update date:2022-08-04
Topics:
Kawano, Tomikazu
Kato, Takahiro
Du, Chong-Xu
Ueda, Ikuo
The reaction of oligo(2-ethynylpyridines) (L1-L8) with copper(I) ions proceeded smoothly to afford tri-, tetra-, and pentanuclear triple-stranded helicates (CL1-CL8) in good yields. If a chiral ligand was used, the stereoselective self-assembly of chiral helicates with one particular chirality was achieved in the solid state. Racemization of copper(I) helicates was also observed in solution.
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