Journal of Fluorine Chemistry p. 103 - 108 (1995)
Update date:2022-07-30
Topics:
Benefice-Malouet, S.
Commeyras, A.
The reactivity of perfluorohexyl iodide with N,N-disubstituted amides or ethyl formate as solvents and reactants, in the presence of a zinc-copper metal couple and radical initiator, has been investigated.In each case, the corresponding perfluorinated carbonyl compounds, such as aldehydes, amides, ketones and esters, were obtained in good yield, thus proving the efficacy of this reaction.The influence of the radical initiator on the reaction mechanisms has been studied and is discussed. - Keywords: Reactivity; Perfluorohexyl iodide; Disubstituted amines; Zinc-copper metal couple; Radical initiator; NMR spectroscopy; IR spectroscopy; Mass spectrometry
View MoreShanghai Mokai Pharmaceutical Co.,Ltd
Contact:021-60257269
Address:Rm506,No.915,Zhenbei Road,Shanghai,200333,China
Contact:+86 512 6287 2180
Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
Shanghai Micro-mega Industry Co., Ltd.
Contact:0086-21-34628682;57153848
Address:Rm413,No.413,West Meilong Road, Minhang District,Shanghai P R China
Contact:+86 18616952870
Address:Area
Triumph International Development Limilted
website:http://www.jiashengchem.cn/
Contact:+86-536-7971999
Address:Yinhai Road,Shouguang
Doi:10.1016/j.tetlet.2019.05.066
(2019)Doi:10.1002/hlca.200390132
(2003)Doi:10.1016/S0040-4039(00)92545-0
(1976)Doi:10.1080/10426500490428906
(2004)Doi:10.1007/BF01156273
()Doi:10.1016/0304-4165(72)90336-4
(1972)
