Bulletin of the Chemical Society of Japan p. 2351 - 2353 (1994)
Update date:2022-08-05
Topics:
Arata, Kazushi
Nakamura, Hideo
Nakamura, Yuki
The title reactions were carried out over seven catalysts.From cyclooctene oxide a large amount of 7-octenal was formed together with 3-cycloocten-1-ol over SiO2-Al2O3 and SiO2-TiO2, 3-cycloocten-1-ol over solid H3PO4, and cyclooctanone over FeSO4.Most catalysts except for NiSO4, Al2O3, and Tio2-ZrO2 produced 1,3-cyclododecadiene, cyclododecanone, and 2-cyclododecen-1-ol uniformly from cyclododecene oxide.Allylic alcohols were preferentially given by Al2O3 and TiO2-ZrO2.
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