Angewandte Chemie - International Edition p. 10635 - 10638 (2013)
Update date:2022-09-26
Topics: Oxidative Addition Chemical Reaction Aromatic compounds Carboiodination
Petrone, David A.
Lischka, Matthias
Lautens, Mark
An I for an I: Conditions for the intramolecular carboiodination and the simultaneous convergent intramolecular carboiodination/intermolecular Heck reaction of various diiodoarenes were developed. The ability of the Pd 0/QPhos catalyst/ligand combination to undergo reversible oxidative addition allows these reactions to proceed well, thus increasing both the appeal and utility of this class of substrates in site-selective cross-coupling reactions. Copyright
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