STEREOSELECTIVE TOTAL SYNTHESIS OF RACEMIC GRANDISOL via 3-OXIMINO-1,4,4-TRIMETHYLBICYCLOHEPTANE. AN IMPROVED PRACTICAL PROCEDURE.

DOI: 10.1016/S0040-4020(01)96088-0

Source and publish data:

Tetrahedron p. 6027 - 6032 (1986)

Update date:2022-08-04

Topics:

Authors:

Rosini, Goffredo

Geier, Monika

Marotta, Emanuela

Petrini, Marino

Ballini, Roberto

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Article abstract of DOI:10.1016/S0040-4020(01)96088-0

(+/-)Grandisol was stereoselectively obtained via 1,4,4-trimethylbicyclo<3.2.0>heptane-3-one and its oxime by an improved procedure. 2,5,5-trimethylhept-1,6-dien-4-ol, the open chain molecule, was synthesized by two routes.Its conversion into (+/-)grandisol was performed emploing the photobicyclization as key step.

Full text of DOI:10.1016/S0040-4020(01)96088-0

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