A short efficient synthesis of ambraketal (four steps) and epiambraketal (five steps) from sclareol

DOI: 10.1016/0040-4039(94)88171-5

Source and publish data:

Tetrahedron Letters p. 97 - 98 (1994)

Update date:2022-08-03

Topics:

Authors:

Martres, Paul

Perfetti, Patricia

Zahra, Jean-Pierre

Waegell, Bernard

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Article abstract of DOI:10.1016/0040-4039(94)88171-5

Ambraketal 7 and epiambraketal 8 are synthesized efficiently from sclareol 1. The key intermediate 5 is obtained by a regioselective elimination of ketoacetate 4 resulting from the side chain oxidative degradation of 1 by ruthenium tetroxide generated in situ.

Full text of DOI:10.1016/0040-4039(94)88171-5

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