Tetrahedron Letters p. 817 - 820 (1984)
Update date:2022-08-03
Topics:
Mattay, Jochen
Gersdorf, Joachim
Freudenberg, Ulrich
The thermal and photochemical reactions of biacetyl 1 and 1,1-diethoxyethene 2 are totally complementary: 1 and 2 exclusively form the 2,2-diethoxyoxetane 4 in polar solvents at room temperature.Contrary to the literature this thermal cycloaddition proceeds uncatalyzed. 1 and 2 react photochemically under exclusive formation of the regioisomer oxetane 3 - preferably in nonpolar solvents.The inversion ("Umpolung") of the reactivity of 1 is caused by the photoinduced electron transfer.
View MoreContact:86-551-63540590
Address:No 1388 Furong Rd., Hefei, Anhui, China
Quzhou Ruiyuan chemical Co., Ltd
Contact:+86-570-3039321/3039361/3039308
Address:18# Huayang Road,Quzhou High-tech Industrial Park, Zhejiang China.
JiangXi Keyuan Biopharma Co., LTD.
Contact:+86-563-6833666
Address:Guangde Fine Chemical Zone, Anhui Province, China
website:http://www.fwdchem.com
Contact:86-21-54450828
Address:Room 802,Lotus Tower ,159 Tianzhou Road,Xuhui District,Shanghai
Shijiazhuang Sdyano Fine Chemical Co., Ltd
Contact:+86-311-89830448
Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China
Doi:10.1002/hlca.200390328
(2003)Doi:10.1021/jo00384a037
(1987)Doi:10.1021/ja00480a031
(1978)Doi:10.1002/jps.2600670433
(1978)Doi:10.1134/S1070363206050288
(2006)Doi:10.1016/j.bioorg.2014.10.006
(2014)
