Journal of Chemical Thermodynamics p. 283 - 292 (1989)
Update date:2022-08-05
Topics:
Airoldi, Claudio
Souza, Antonio G. de
The standard molar enthalpies of formation of crystalline tris(di-n-butyldithiocarbamato)E(III), (E = P, As, Sb, or Bi), determined at 298.15 K by solution-reaction calorimetry, are -(705.5 +/- 7.3), -(443.1 +/- 5.4), -(526.2 +/- 2.5), and -(530.7 +/- 5.5) kJ*mol-1, respectively.The enthalpies of sublimation: (136 +/- 3), (128 +/- 3), (179 +/- 3), and (202 +/- 3) kJ*mol-1, were estimated.From the enthalpies of formation of the gaseous complexes, the homolytic and heterolytic mean standard molar element-sulphur bond enthalpies were calculated.These values are correlated with element-sulphur bond distances, and a larger phosphorus- sulphur bond enthalpy reflects a better overlap of d orbitals in bonding formation.
View Morewebsite:http://www.lidepharma.com
Contact:+86-25-58409506
Address:11F, Building A1, No.288 North Zhongshan Road, Gulou District, Nanjing,210003, P.R.China.
Contact:+86-571-87010026
Address:202, Zhenhua Road,
Tianjin Tensing Fine Chemical Research Develop Centre
Contact:86-022-23718576,13032267585
Address:2-2-201,13 Guiyuan road,Huayuan Industry district,Tianjin,china
Contact:+86-577-65618087-605
Address:Room 402, Unit 4 Xinhu Bldg. Waitan Ruian City, Zhejiang China.
Hangzhou Haiqiang Chemical Co.,Ltd.
Contact:+86-571-86960370
Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
Doi:10.1007/BF02226518
(1995)Doi:10.1021/acs.jmedchem.8b00971
(2018)Doi:10.1021/ic50224a035
(1981)Doi:10.1039/jr9500000384
(1950)Doi:10.1016/S0040-4020(01)97731-2
(1981)Doi:10.1039/P19810001473
(1981)