Journal of Organic Chemistry p. 2355 - 2360 (1984)
Update date:2022-08-04
Topics:
Feigenbaum, Alexandre
Pete, Jean-Pierre
Scholler, Denise
3-Aryl-1,2-cyclohexanediones 4 are prepared conveniently by photolysis of the corresponding 2-((arylsulfonyl)oxy)cyclohex-2-enones 1.The reaction was shown to occur from a triplet excited state.A biphotonic process involving the normal photo-Fries product 14 as an intermediate was ruled out by preparing and irradiating this compound.The difference of reactivity between 1 and 2-((arylsulfonyl)amido)cyclohexenones is discussed.
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