Reactions of group 4 metallocene alkyne complexes with carbodiimides: Experimental and theoretical studies of the structure and bonding of five-membered hetero-metallacycloallenes

Article abstract of DOI:10.1021/ja111479j

The reaction of the low-valent metallocene(II) sources Cp ₂Ti(n²-Me₃SiC₂SiMe₃) (7) and Cp₂Zr(py)(n²-Me₃SiC₂SiMe ₃) (11, Cp = n⁵-cyclopentadienyl, py = pyridine) with carbodiimides RN=C=NR (R = Cy, i-Pr, p-Tol) leads to the formation of five membered hetero-metallacycloallenes Cp₂M{Me₃SiC=C= C[N(SiMe₃)(R)]-N(R)} (9M-R) (M = Ti, R = i-Pr; M = Zr, R = Cy, i-Pr, p-Tol). Elimination of the alkyne (as the hitherto known reactivity of titanocene and zirconocene alkyne complexes would suggest) was not observed. The molecular structures of the obtained complexes were confirmed by X-ray studies. Moreover, the structure and bonding of the complexes 9Zr-Cy and 9Zr-p-Tol was investigated by DFT calculations.(Figure Presented)