Highly Diastereoselective Reduction of Chiral β-Ketosulphoxides under Chelation Control: Application to the Synthesis of (R)-(+)-n-Hexadecano-1,5-lactone

DOI: 10.1039/c39850000211

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Journal of the Chemical Society. Chemical communications p. 211 - 213 (1985)

Update date:2022-08-05

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Authors:

Kosugi, Hiroshi

Konta, Hiroshi

Uda, Hisashi

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Article abstract of DOI:10.1039/c39850000211

The presence of zinc chloride in the reduction of chiral β-ketosulphoxides with di-isobutylaluminium hydride effects high 1,3-asymmetric induction to give β-hydroxysulphoxides; this method can be successfully applied to the synthesis of optically pure 1,4

Full text of DOI:10.1039/c39850000211

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