Inorganic Chemistry p. 1132 - 1141 (1980)
Update date:2022-07-30
Topics:
Freeman, Michael B.
Hall, Laurence W.
Sneddon, Larry G.
The reactions of cobalt atoms and cyclopentadiene with various alkynes such as hexafluorobutyne, trifluoropropyne, and diphenylacetylene have been found to yield a variety of new organometallic compounds including both mono- and multimetal complexes. In general the products obtained fall into four categories: (1) complexes containing ligands resulting from dimerization or trimerization of the alkyne usually accompanied by hydrogen addition, i.e., (η-C5H5)Co[C4H2(CF 3)4], (η-C5H5)2Co2[C5H 2F(CF3)3], (η-C5H5)2Co2[C6H 5(CF3)3], [η,-C5(CH3)5]Co[C4H 2(CF3)4], (η-C5H5)2Co2[C2H 2(CF3)]2, and (η-C5H5)Co[C4(C6H 5)4]; (2) multimetal clusters containing cyclopentadienylcobalt units and alkynes, i.e., (η-C5H5)3Co3[C 2(CF3)2], (η-C5H5)3Co3[C 2(CF3)2](μ3-CO), and [η-C5(CH3)5]2Co 2[C2(CF3)2]2; (3) complexes containing ligands resulting from cycloadditions of cyclopentadiene and alkynes, i.e., (η-C5H5)Co[C7H6(CF 3)2] and (η-C5H5)Co[C9H6(CF 3)4]; (4) complexes containing ligands resulting from simple additions of cyclopentadiene and alkynes, i.e., (η-C5H5)2Co2[C7H 8(CF3)2], (η-C5H5)2Co2[C9H 4(CF3)4], (η-C5H5)2Co2[C9H 6(CF3)4], and (η-C5H5)Co[C9H6(C 6H5)4]. The nature of these products implies the formation of certain reactive cyclopentadienylcobalt intermediates in these metal atom reactions, and an appropriate reaction scheme is discussed.
lianyungang jinkang pharmaceutical technology co., ltd.
Contact:008651885445517
Address:Jinshan industrial park, Ganyu county, Lianyungang, Jiangsu Province, 222115, China
Shenyang NovPharm Technology Co., Ltd.
Contact:.+86-24-24165786
Address:Room 306, Hongjin Mansion, No. 36-1, Wanliutang Rd., Shenhe District, Shenyang, Liaoning, P.R.C.
Zibo Ocean International Trade Co.,Ltd(expird)
Contact:+86 533 5160706
Address:1117, Hongtai Bld., Songling rd, Zichuan,Zibo,Shandong,China
Haitong Chemical Industrial Co.,Ltd.
website:https://www.haitonglongwin.com/
Contact:+86-022-66221018
Address:18-701, No.99, The 4th Street, TEDA,
SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD
Contact:+86-576-88685096
Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.
Doi:10.1021/acs.orglett.5b00196
(2015)Doi:10.13005/ojc/350215
(2019)Doi:10.1039/P19810002615
(1981)Doi:10.1016/S0040-4020(01)93736-6
(1979)Doi:10.1021/jo01299a030
(1980)Doi:10.1271/bbb.69.374
(2005)
