Journal of the Chemical Society. Perkin transactions II p. 1361 - 1368 (1984)
Update date:2022-08-05
Topics:
Sopher, David W.
Utley, James H. P.
The presence of chromium(III) chloride, both hydrated and anhydrous, profoundly alters the course of cathodic in dimethylformamide solutions of benzophenone, benzaldehyde, β-ionone, β-ionylidene acetaldehyde, and retinal.Pinacolisation is enhanced at the expense of formation of the corresponding alcohol.Furthermore the relevant reduction potential is lowered.The mechanism of the reaction has been investigated using voltammetric and coulometric experiments combined with a detailed analysis of preparative-scale reductions under a variety of conditions.The stereochemical course of the reactions has also been considered.In total the results provide compelling evidence in favour of the key reducible intermediate being a carbonyl compound-Cr(III) complex which is formed via the corresponding Cr(III) species with homogenous, inner sphere, re-oxidation playing a crucial role.This is contrary to earlier suggestions invoking the participation of electrogenerated Cr(II) as the reductant.
View MoreQuhua Zhongxing Refrigeration Technology Co.,Ltd.
Contact:+86-5708886618
Address:318 Bulding 2, No.866 Quhua Rd.,Kecheng District
Chengdu ZY Biochemical Technology Co., LTD
Contact:0086-28-88680086
Address:170 Qingpu Road, Shouan Town, Pujiang County
NanJing KaiHeng Chemical CO., LTD.
Contact:+86-25-85768391
Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA
LABTER PARMATECH(BEIJING)CO.,LTD
website:http://www.labter.com.cn/
Contact:+86-10-56330744
Address:NO.19,TIANRONG STREET,DAXING BIOMEDICIAL BASE ,ZHONGGUANCUN SCIENCE AND TECHNOLOGY PARK,BEIJING ,CHINA
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.
Contact:+86-512-6585 6968
Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China
Doi:10.3987/com-97-7934
(1998)Doi:10.1016/s0020-1693(97)05832-5
(1998)Doi:10.1080/10426509608545200
(1996)Doi:10.3987/COM-97-S(N)108
(1998)Doi:10.1039/DT9950003473
(1995)Doi:10.1039/j39680002091
(1968)
