Hydrocarbon Complexes of Iron, Ruthenium, and Osmium. Part 14. Reactions of a Disilicon-chelated Carbonylruthenium Complex with Cyclic Polyolefins

DOI: 10.1039/DT9800000545

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 545 - 551 (1980)

Update date:2022-08-02

Topics:

Authors:

Edwards, Julie D.

Knox, Selby A. R.

Stone, F. Gordon A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9800000545

The complex undergoes reactions with cycloheptatriene and cyclo-octatriene such that one or both silicon atoms of chelate ligand migrate to the co-ordinated polyolefin.From C7H8 the cyclopentadienyl complex is produced and converted into the cyclohepta-1,3-diene complex upon treatment with CO.Similar behaviour is observed using 7-C6F5C7H7.Cyclo-octatriene yields fully migrated directly, as well as the diruthenium complex containing an unusual η⁷-hydrocarbon ligand bridging the two metal atoms.Cyclopentadiene reacts with to give a complex <(OC)2(η-C5H5)RuSiMe2CH2CH2Me2SiRu(η-C5H5)(CO)2> in which the disilicon chelate links two ruthenium atoms.

Full text of DOI:10.1039/DT9800000545

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[RuC₇H₈(Si(CH₃)2CH₂CH₂Si(CH₃)2)(CO)3]

Cas No:74042-71-0

R&D Labs maybe for 74042-71-0

Zhejiang kehong chemical co., ltd

Contact:0086-575-85522000

Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073
SHANGHAI BIOSUNDRUG CO.,LTD.

Contact:86-21-34622192，13917187091，21-34622765

Address:No. 500 Caobao Road Shanghai P.R China
Taixing Joxin Bio-tec Co.,Ltd.

website:http://www.joxbio.com

Contact:86-523-87558858 87612088

Address:No.88, chengdong industrial park
Anhui Hope-Chem Co., Ltd.

Contact:86-551-63540590

Address:No 1388 Furong Rd., Hefei, Anhui, China
SHANDONG AONA CHEMICAL CO.,LTD.

Contact:86-532-85762926

Address:LIUYUAN TOWN, ZAOZHUANG CITY, SHANGDONG PROVINCE.

Relevant to this article

Folate analogues altered in the C⁹-N¹⁰ bridge region. XVI. Synthesis and antifolate activity of 11-thiohomoaminopterin

Doi:10.1021/jm00182a017
(1980)
Flash photolytic generation of primary, secondary, and tertiary ynamines in aqueous solution and study of their carbon-protonation reactions in that medium

Doi:10.1021/ja9601797
(1996)
Oxyguanidines. Part 2: Discovery of a novel orally active thrombin inhibitor through structure-based drug design and parallel synthesis

Doi:10.1016/j.bmcl.2004.05.002
(2004)
Doi:10.1080/10473289.2001.10464257
(1938)
A new series of cyclic amino acids as inhibitors of S-adenosyl L- methionine synthetase

Doi:10.1016/S0960-894X(98)00267-4
(1998)
Fluorescence polarization-based assays for detecting compounds binding to inactive c-Jun N-terminal kinase 3 and p38α mitogen-activated protein kinase

Doi:10.1016/j.ab.2016.02.018
(2016)

Article Doi