Journal of the American Chemical Society p. 7591 - 7599 (1982)
Update date:2022-08-03
Topics:
Danishefsky, Samuel
Morris, Joel
Mullen, George
Gammill, Ronald
Diels-Alder cycloaddition of dienophile 26 with diene 8 produces the protected 4-aryl-4-acylcyclohexadienone 37.This is converted in two steps to the oxidized mesembrine derivative 11.Through the novel use of trimethyl orthoformate as a C1 inte
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