THE STEREOCHEMISTRY AND MECHANISM OF THE RING OPENING REACTION OF 3-ARYLTETRAZOLOPYRIDINIUM SALTS AND THEIR V-TRIAZOLO ANALOGUES

DOI: 10.1016/S0040-4039(01)85587-8

Source and publish data:

Tetrahedron Letters p. 663 - 666 (1980)

Update date:2022-08-05

Topics:

Authors:

Gelleri, A.

Messmer, A.

Nagy, S.

Radics, L.

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Article abstract of DOI:10.1016/S0040-4039(01)85587-8

Contrary to earlier reports, the title reaction was found to yield both lE and lZ configured dienic products predicted for a disrotatory process.A novel degradation giving, via the loss of one carbon unit, tetrazolyl- and triazolyl-acrolein wasw also observed.

Full text of DOI:10.1016/S0040-4039(01)85587-8

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