Regiochemical Control of the Addition of Aryl Selenols and Aryl Thiols to the Triple Bond of Arylpropiolates. Synthesis of Seleno- and Thioflavones and Seleno- and Thioaurones

DOI: 10.1021/jo01311a013

Source and publish data:

Journal of Organic Chemistry p. 4611 - 4615 (1980)

Update date:2022-09-26

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Authors:

Wadsworth, Donald H.

Detty, Michael R.

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Article abstract of DOI:10.1021/jo01311a013

Addition of aryl selenols and aryl thiols to arylpropiolates under basic conditions followed by saponification gave exclusively β-substituted cinnamates of predominant Z sterochemistry.Neat solutions of aryl selenols or aryl thiols and arylpropiolates aft

Full text of DOI:10.1021/jo01311a013

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