Journal of the Chemical Society. Perkin transactions I p. 1477 - 1486 (1980)
Update date:2022-08-03
Topics:
Laird, Trevor
Ollis, W. David
Sutherland, Ian O.
The base catalysed rearrangements of the cations (1d-j) in aqueous solution yield the isomeric cations (15) or the aldehydes (10) and (11), or mixtures of (15), (10), and (11).This contrasts dramatically with the transformations observed for the cations (1) in aprotic solvents.The cations (15) undergo Hofmann elimination to the naphthalenic amines (12) or (13) and (14).The methiodide of amine (13g) shows a novel consequence of restricted rotation.The n.m.r. spectrum of the methiodide shows that the two protons of the methylene group are diastereotopic.
View MoreLaizhou City Laiyu Chemical CO.,Ltd
Contact:+86-535-2719337/2719339
Address:Chenggang road zhuyou laizhou City Shangdong China
Shanghai Science Peptide Biological Technology Co.,ltd
website:http://www.scipeptide.com
Contact:+86-21-51099675
Address:No.8 Changyang Rd
Zouping Mingxing Chemical Co.,Ltd.
website:http://www.zoutong.com.cn
Contact:86-543-2240068 2240067
Address:428 Daixi Third Road Zouping County Shandong Province China
Shanghai Micro-mega Industry Co., Ltd.
Contact:0086-21-34628682;57153848
Address:Rm413,No.413,West Meilong Road, Minhang District,Shanghai P R China
Xiamen Goodhealth Pharmchem Co., Ltd.
Contact:0086-592-2097683
Address:404R No.2 54# Minzu Rd., Xiamen, China
Doi:10.1021/ja01605a027
(1956)Doi:10.1021/jo01102a025
(1958)Doi:10.1021/jo01057a040
(1962)Doi:10.1021/acs.joc.5b01014
(2015)Doi:10.1016/0040-4039(81)80069-X
(1981)Doi:10.1016/j.bmcl.2004.05.087
(2004)
