Journal of Organic Chemistry p. 312 - 315 (1981)
Update date:2022-08-05
Topics: Characterization Workup Materials Reaction
Brittelli, David R.
Boswell, George A.
The reaction of α-ethynyl acetates with NOF/NOBF4 yields 3,4-bis<(acetoxycycloalkyl)carbonyl>furoxans.The presence of the α-acetoxy substituent is necessary for the reaction to proceed.The course of the reaction is rationalized by invoking the intermediacy of a nitroacetylene, which dimerizes with rearrangement to afford the observed product.
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Doi:10.1039/jr9610003448
(1961)Doi:10.1007/BF00903317
(1980)Doi:10.1246/bcsj.54.985
(1981)Doi:10.1021/ja01490a062
(1960)Doi:10.1016/S0040-4039(00)78650-3
(1980)Doi:10.1021/jm060381c
(2007)