Chemistry Letters p. 1071 - 1074 (1980)
Update date:2022-08-05
Topics:
Nakadaira, Yasuhiro
Sakaba, Hiroyuki
Sakurai, Hideki
6,6-Dimethyl-6-silafulvene generated from (allyl)(cyclopentadienyl)-dimethylsilane reacts with a trapping reagent such as methanol, benzaldehyde, and benzophenone to give (cyclopentadienyl)(methoxy)dimethylsilane, 6-phenylfulvene, and 6,6-diphenylfulvene, respectively.Without a trapping reagent, the silafulvene undergoes dimerization.
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Doi:10.1248/cpb.28.2839
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()Doi:10.1021/ja047190o
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