Tetrahedron p. 1643 - 1647 (1980)
Update date:2022-09-26
Topics: NMR spectroscopy Amines aryl groups Reaction Experimental study
Katritzky, Alan R.
Brownlee, Robert T.C.
Musumarra, Giuseppe
The reaction of primary and secondary amines with 2,4,6-triarylpyryliums is shown by C-13 NMR to proceed by fast ring opening to a vinylogous amide; in the case of primary amines this closes slowly to a pyridinium salt. The reaction in DMSO gives the pyridinium salt quantitatively when 2 moles of amines are used, with less amine significant quantities of a diketone intermediate are produced which results in slower conversion.
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Doi:10.1016/j.ejmech.2011.12.026
(2012)Doi:10.1021/ja01331a056
(1933)Doi:10.1246/cl.1974.1261
(1974)Doi:10.1002/adsc.200390036
(2003)Doi:10.1016/S0040-4020(01)97555-6
(1974)Doi:10.1016/0040-4039(96)01822-9
(1996)
