SYNTHESIS OF THE PENTACARBONYL(CHALCOCARBONYL)CHROMIUM(0) COMPLEXES, Cr(CO)5(CX) (X = S, Se)

DOI: 10.1016/S0022-328X(00)81474-6

Source and publish data:

Journal of Organometallic Chemistry p. 177 - 183 (1981)

Update date:2022-09-26

Topics:

Authors:

English, Ann M.

Plowman, Keith R.

Baibich, Ione M.

Hickey, James P.

Butler, Ian S.

et al. et al.

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Article abstract of DOI:10.1016/S0022-328X(00)81474-6

The arene complexes, (η⁶-C6H6)Cr(CO)2(CX) (X = S, Se), react with excess CO gas under pressure in tetrahydrofuran at about 60 deg C to produce the Cr(CO)5(CX) complexes in high yield.The IR and NMR (13C and 17O) spectra of these complexes are i

Full text of DOI:10.1016/S0022-328X(00)81474-6

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Product name:{(C₆H₅)3PNP(C₆H₅)3}⁽¹⁺⁾*{Cr(CO)4(CS)Cl}^(1-)={(C₆H₅)3PNP(C₆H₅)3}{Cr(CO)4(CS)Cl}

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