Highly stereoselective reductions of α-alkoxy-β-keto esters. Aspects of the mechanism of sodium borohydride reduction of ketones in 2-propanol

DOI: 10.1016/0040-4039(80)80101-8

Source and publish data:

Tetrahedron Letters p. 2467 - 2470 (1980)

Update date:2022-08-04

Topics:

Authors:

Glass, Richard S.

Deardorff, Donald R.

Henegar, Kevin

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Article abstract of DOI:10.1016/0040-4039(80)80101-8

Reduction of α-alkoxy-β-keto esters with sodium borohydride in 2-propanol proceeds with high stereoselectivity via a five-membered ring chelated sodium ion.

Full text of DOI:10.1016/0040-4039(80)80101-8

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