Highly stereoselective reductions of α-alkoxy-β-keto esters. Aspects of the mechanism of sodium borohydride reduction of ketones in 2-propanol

DOI: 10.1016/0040-4039(80)80101-8

Source and publish data:

Tetrahedron Letters p. 2467 - 2470 (1980)

Update date:2022-08-04

Topics:

Authors:

Glass, Richard S.

Deardorff, Donald R.

Henegar, Kevin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(80)80101-8

Reduction of α-alkoxy-β-keto esters with sodium borohydride in 2-propanol proceeds with high stereoselectivity via a five-membered ring chelated sodium ion.

Full text of DOI:10.1016/0040-4039(80)80101-8

Products guided by the article

Product name:3-Hydroxy-2-methoxy-3-phenyl-propionic acid tert-butyl ester

Cas No:76801-15-5

R&D Labs maybe for 76801-15-5

Huayang chemical Co., LTD

Contact:+86-18653358619

Address:zibo
Rugao Jinling Chemical Co., Ltd.(expird)

Contact:0086-513-68005586

Address:Lianluo new village huangshi town Rugao city Jiangsu Province.
Daqing New Century Fine Chemical Co., Ltd.(expird)

Contact:010-57126694

Address:No.39, jinxing cun, honggang district
Shreeji pharma international

Contact:0091-265-2313036

Address:311, ATLANTIS HEIGHTS SARABHAI MAIN ROAD,VADIWADI ,VADODARA
NingBO Hong Xiang Biochem.Co.Ltd

website:http://www.hxbiochem.com

Contact:0574-66003444

Address:Ning Bo Bei Lun

Relevant to this article

The trans-Influence in Platinum(II) Complexes. 1H- and 13C-NMR. and X-Ray Structural Studies of Tridentate Schiff's Base Complexes of Platinum(II)

Doi:10.1002/hlca.19800630734
(1980)
Doi:10.1021/jo01348a058
(1966)
Synthesis of (-)-Conduramine A1, (-)-Conduramine A2 and (-)-Conduramine E2 in Six Steps from Cyclohexa-1,4-diene

Doi:10.1021/acs.orglett.9b02914
(2019)
Self-assembly by ligand disassembly? - Formation of an unusual dodecanuclear [Co(II)₆Co(III)₆] cluster

Doi:10.1039/b405131a
(2004)
Palladium-Catalyzed Cross-Coupling of Stereospecific Potassium Cyclopropyl Trifluoroborates with Aryl Bromides

Doi:10.1021/ol036184e
(2004)
Catalytic enantioselective Michael addition of 1,3-dicarbonyl compounds to nitroalkenes catalyzed by well-defined chiral Ru amido complexes

Doi:10.1021/ja046296g
(2004)

Article Doi