Stereoselective crossed aldol reaction via boron enolate generated from α-iodoketones and 9-BBN-H

DOI: 10.1246/cl.2002.698

Source and publish data:

Chemistry Letters p. 698 - 699 (2002)

Update date:2022-08-04

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Authors:

Mukaiyama, Teruaki

Imachi, Shouhei

Yamane, Keiko

Mizuta, Masahiro

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Article abstract of DOI:10.1246/cl.2002.698

Boron enolates were in situ generated smoothly by treating α-iodo ketones with 9-BBN-H, and aldols were produced in highly diastereoselective manner by successive reaction with various aldehydes at low temperature.

Full text of DOI:10.1246/cl.2002.698

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