Reactivity of Tetra-n-butylammonium Di-μ-chloro-bis. A General Method for the Synthesis of cis Isomers of Neutral and Anionic Palladium(II) Complexes

DOI: 10.1039/DT9810000463

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 463 - 465 (1981)

Update date:2022-08-05

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Authors:

Uson, Rafael

Fornies, Juan

Espinet, Pablo

Martinez, Francisco

Tomas, Milagros

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Article abstract of DOI:10.1039/DT9810000463

The reaction of n4>2 with L (L = N, P, As, or Sb donor ligand) leads to the synthesis of novel anionic palladium complexes of the type n4>, which react with L to give the neutral complexes .Both families of compounds are the cis derivatives.Moreover, replacement of Cl by SCN or CN, and of L (SbPh3 or AsPh3) by PPh3, takes place without a change in configuration, giving again cis isomers.

Full text of DOI:10.1039/DT9810000463

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