Sulfoxide-controlled SN2′ displacements between cuprates and vinyl and alkynyl epoxy sulfoxides

DOI: 10.1016/j.tet.2004.06.092

Source and publish data:

Tetrahedron p. 8171 - 8180 (2004)

Update date:2022-08-04

Topics:

Authors:

Fernández De La Pradilla, Roberto

Viso, Alma

Castro, Sonia

Fernández, Jorge

Manzano, Pilar

Tortosa, Mariola

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Article abstract of DOI:10.1016/j.tet.2004.06.092

The S_N2′ displacement of readily available vinyl epoxy sulfoxides with organocopper reagents takes place in good yields with high anti selectivity and a good degree of E/Z stereocontrol to produce enantiopure α-hydroxy vinyl sulfoxides. A secon

Full text of DOI:10.1016/j.tet.2004.06.092

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