
Tetrahedron Letters p. 1137 - 1140 (1994)
Update date:2022-07-30
Topics:
Koch, Kevin
Smitrovich, Jacqueline H.
Various aryl substituted enones are reduced using lithium aluminum hydride to afford sterioselectively trans substituted alkanols.Mechanistic studies demonstrate 1,2-addition followed by hydroxy-directed hydroalumination of the conjugated styryl unit.
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(1940)