Journal of Organic Chemistry p. 3634 - 3638 (1981)
Update date:2022-08-04
Topics:
Khuthier, Abdul-Hussain
Al-Kazzaz, Abdul-Khalik S.
Al-Rawi, Jasim M. A.
Al-Iraqi, Mohammed A.
Substituted N-aryl cyclic amine oxides undergo novel thermal rearrangement to O-arylhydroxylamines.Electron-withdrawing substituents are essential for the rearrangement and must be ortho or para relative to the N->O function.The mechanism of the rearrangement is best described by an intramolecular cyclic process.Kinetic results are in agreement with the cyclic process but are inconsistent with a homolytic dissociation-recombination mechanism.
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