Journal of Organic Chemistry p. 3634 - 3638 (1981)
Update date:2022-08-04
Topics:
Khuthier, Abdul-Hussain
Al-Kazzaz, Abdul-Khalik S.
Al-Rawi, Jasim M. A.
Al-Iraqi, Mohammed A.
Substituted N-aryl cyclic amine oxides undergo novel thermal rearrangement to O-arylhydroxylamines.Electron-withdrawing substituents are essential for the rearrangement and must be ortho or para relative to the N->O function.The mechanism of the rearrangement is best described by an intramolecular cyclic process.Kinetic results are in agreement with the cyclic process but are inconsistent with a homolytic dissociation-recombination mechanism.
View MoreBeijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)
website:http://www.bjgreenchem.com/
Contact:+86-427-6515887
Address:301,302, 3rd Floor, Building C-7, Dongsheng Science Park, Northern Territory, Zhongguancun, No. 66, Xixiaokou Road, Haidian District, Beijing
AUSHUN PHARMACEUTICAL TECHNOLOGY CO,.LTD
Contact:+86-25-86883560 15951806178
Address:14 Dayingbi, Zhujiang Rd. East, Nanjing, Jiangsu, China.
SHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD
Contact:+86-755-82412922
Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District
Shanghai Hohance Chemical Co., ltd
Contact:13914753421
Address:Fl.5;Bld. 70, Lane 1500; Xinfei Road
Contact:+86-0760-85282375
Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Doi:10.1021/jo00333a036
(1981)Doi:10.1021/ja0477221
(2004)Doi:10.1021/ja00403a041
(1981)Doi:10.1021/jm00142a023
(1981)Doi:10.1021/acs.jmedchem.7b00030
(2017)Doi:10.1021/om970709n
(1998)