Journal of the Chemical Society. Perkin transactions I p. 1815 - 1820 (1981)
Update date:2022-09-26
Topics:
Koppes, William M.
Lawrence, G. William
Sitzmann, Michael E.
Adolph, Horst G.
1,3,5-Trifluorotrinitrobenzene (1) is shown to be a versatile intermediate for the preparation of symmetrical and unsymmetrical 1,3,5-trisubstituted trinitrobenzene derivatives.Its reaction with a number of representative N, O, C, and halogen nucleophiles is described.An unusually large cation effect is reported for its reaction with the ambident anion of dinitromethane.
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Doi:10.1021/jo01014a006
(1965)Doi:10.1016/S0040-4039(01)81770-6
(1981)Doi:10.1039/b407820a
(2004)Doi:10.1002/anie.200454111
(2004)Doi:10.1007/BF00503654
(1982)Doi:10.1021/jo01362a034
(1957)
