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128-08-5

Basic Information
CAS No.: 128-08-5
Name: N-Bromosuccinimide
Article Data: 40
Cas Database
Molecular Structure:
Molecular Structure of 128-08-5 (N-Bromosuccinimide)
Formula: C4H4BrNO2
Molecular Weight: 177.985
Synonyms: N-Bromosuccinimide;N-bromobutanimide;1-Bromopyrrolidine-2,5-dione;1-bromopyrrolidine-2,5-dione;
EINECS: 204-877-2
Density: 2.042 g/cm3
Melting Point: 173- 176°C
Boiling Point: 221.4 °C at 760 mmHg
Flash Point: 87.7 °C
Solubility: Soluble in acetone, tetrahydrofuran, dimethyl formamide, dimethyl sulfoxide and acetonitrile. Slightly soluble in water and acetic acid. Insoluble in ether, hexane and carbon tetrachloride.
Appearance: white to off-white powder
Hazard Symbols: CorrosiveC,HarmfulXn
Risk Codes: 22-34-36/37/38
Safety: 26-36/37/39-45-37/39
Transport Information: UN 3261 8/PG 2
PSA: 37.38000
LogP: 0.38320
Synthetic route
123-56-8

Succinimide

128-08-5

N-Bromosuccinimide

Conditions
ConditionsYield
With hydrogenchloride; sodium chlorite; sodium bromide In water at 0 - 25℃; for 1.5h; Temperature;96%
With sodium bromate; sulfuric acid; hydrogen bromide In water for 0.166667h; Ambient temperature;95%
With [bis(acetoxy)iodo]benzene In tetrachloromethane at 20℃; Solvent;94%
123-56-8

Succinimide

79-15-2

N-bromoacetamide

128-08-5

N-Bromosuccinimide

128-09-6

N-chloro-succinimide

128-08-5

N-Bromosuccinimide

Conditions
ConditionsYield
With tetraethylammonium bromide halogen exchange durin complex formation between an N-halogensuccinimide and quaternary ammonium halide;
With water; sodium bromide
82815-39-2

benzotelluracyclopentane bromide succinimide

A

128-08-5

N-Bromosuccinimide

B

1,1-dibromo-3,4-benzo-1-telluracyclopentane

Conditions
ConditionsYield
With bromine Te-N cleavage;
123-56-8

Succinimide

7726-95-6

bromine

furan-2,3,5(4H)-trione pyridine (1:1)

128-08-5

N-Bromosuccinimide

123-56-8

Succinimide

hypobromous acid

hypobromous acid

128-08-5

N-Bromosuccinimide

123-56-8

Succinimide

A

128-08-5

N-Bromosuccinimide

B

H2O

H2O

Conditions
ConditionsYield
Equilibrium constant;
123-56-8

Succinimide

A

128-08-5

N-Bromosuccinimide

B

HBr

HBr

Conditions
ConditionsYield
With bromine Equilibrium constant;

2-(4-methylphenyl)-2-(N-bromo-p-toluene-sulfonamide)-1-bromo-ethane

123-56-8

Succinimide

A

128-08-5

N-Bromosuccinimide

B

2-bromo-1-(4-methylphenyl)-1-(p-toluenesulfonamido)ethane

Conditions
ConditionsYield
In dichloromethane-d2

C21H16BrS(1+)*C4H4NO2(1-)

A

128-08-5

N-Bromosuccinimide

B

74067-58-6

1-methylthiotriptycene

Conditions
ConditionsYield
In dichloromethane-d2 at 22℃; Equilibrium constant; Inert atmosphere; Schlenk technique;
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    N-Bromosuccinimide Product Name: N-Bromosuccinimide Molecular Weight: 177.98 CAS NO: 128-08-5 EC NO: 204-878-8 Molecular Formula: C4H4BrNO

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    Product Name: N-Bromosuccinimide CAS: 128-08-5 MF: C4H4BrNO2 MW: 177.98 EINECS: 204-877-2 Mol File: 128-08-5.mol N-Bromosuccinimide Structure N-Bromosuccinimide Chemical Properties Melting point 175-180 °C (dec.)(lit.) Boi

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  • 2,5-PYRROLIDINEDIONE, 1-BROMO-

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Chemistry

Molecular Structure :

IUPAC Name: 1-bromopyrrolidine-2,5-dione
Empirical Formula: C4H4BrNO2 
Molecular Weight: 177.9841 
Product Categories: Nitrogen cyclic compounds; Medical Intermediates; Biochemistry; Bromination; Halogenation; N-Substituted Maleimides, Succinimides & Phthalimides; N-Substituted Succinimides; Reagents for Oligosaccharide Synthesis; Synthetic Organic Chemistry
Melting Point: 175-180 °C (dec.)(lit.)
Storage temperature: 0-6 °C 
Sensitive: Moisture Sensitive
Stability: Stable. Incompatible with strong oxidizing agents, halogenated hydrocarbons.
Index of Refraction:  1.606 
Surface Tension:  67.8 dyne/cm 
Density:  2.042 g/cm3 
Flash Point:  87.7 °C 
Enthalpy of Vaporization:  45.79 kJ/mol 
Boiling Point:  221.4 °C at 760 mmHg 
Vapour Pressure of  N-Bromosuccinimide (CAS NO.128-08-5):  0.107 mmHg at 25 °C 

Uses

  N-Bromosuccinimide (CAS NO.128-08-5) is a chemical reagent which is used in radical substitution and electrophilic addition reactions in organic chemistry.It also can be considered a convenient source of cationic bromine.

Safety Profile

Hazard Codes CorrosiveC,HarmfulXn
Risk Statements 22-34-36/37/38 
R22:Harmful if swallowed. 
R34:Causes burns. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 26-36/37/39-45-37/39 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S37/39:Wear suitable gloves and eye/face protection.

Specification

  N-Bromosuccinimide (CAS NO.128-08-5), its Synonyms are 2,5-Pyrrolidinedione, 1-bromo- ; 1-Bromo-2,5-pyrrolidinedione ; Akos bbs-00004413 ; Bromosuccinimide ; Bromosuccinimide-n;succinimide, N-bromo- ; Succinbromide ; Succinbromimide . It is white to light yellow crystalline powder.

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