AN APPLICATION OF THE PALLADIUM-CATALYZED, ALLYLIC AMINATION OF UNSATURATED SUGARS: A NEW SYNTHESIS OF D-FOROSAMINE

Article abstract of DOI:10.1016/S0008-6215(00)85594-9

Methyl 4-O-benzoyl-6-bromo-6-deoxy-α-D-glucopyranoside, obtainable from methyl 4,6-O-benzylidene-α-D-glucopyranoside (1), was converted into the 2,3-unsaturated 4-benzoate (3) by application of the triiodoimidazole method.Debenzoylation of 3, followed by