Effect of Chain Length and Heteroatom Position on Ammonium Ion Binding in Nitrogen-containing "Lariat" Ethers

DOI: 10.1039/c39820000242

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 242 - 243 (1982)

Update date:2022-07-29

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Authors:

Schultz, Rose Ann

Schlegel, Eric

Dishong, Dennis M.

Gokel, George W.

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Article abstract of DOI:10.1039/c39820000242

Macrocyclic polyethers having polyethyleneoxy-sidechains extending from a nitrogen pivot bind ammonium ions quite strongly when an 18-membered ring and a two-oxygen sidechain are present; a 15-membered ring and other chain lengths give inferior binding.

Full text of DOI:10.1039/c39820000242

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