Journal of Organic Chemistry p. 342 - 346 (1982)
Update date:2022-08-04
Topics:
Eisenbraun, Edmund J.
Harms, Weldon M.
Palaniswamy, Venkatapuram A.
Chen, Hoffman H.
Porcaro, Peter J.
et al.
4-tert-Butyl-1,1-dimethylindan was synthesized to help establish the identity of products (5- and 6-tert-butyl-1,1-dimethylindan as minor and major products, respectively) from the sulfuric acid catalyzed condensation of tert-butylbenzene and isoprene.NMR (1H and 13C) studies of these hydrocarbons and their corresponding indanones, obtained through chromic acid oxidation, provided structural proof.Gated decoupling experiments were crucial to complete assignment.
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Doi:10.1039/c2ob07157f
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