
Journal of Organic Chemistry p. 1440 - 1456 (1985)
Update date:2022-08-04
Topics:
Nicolaou, K. C.
Papahatjis, D. P.
Claremon, D. A.
Magolda, R. L.
Dolle, R. E.
A highly stereocontrolled and convergent total synthesis of optically active ionophore antibiotic X-14547A (1) was designed and carried out.Degradative reactions led to the key intermediates 3 and 6, which served as convenient comparison stages.The tetrah
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