Oxidation Studies on β-Lactam Antibiotics. The 6-(Diacylamino)penicillins

DOI: 10.1021/jo00360a030

Source and publish data:

Journal of Organic Chemistry p. 1811 - 1815 (1986)

Update date:2022-08-05

Topics:

Authors:

Micetich, Ronald G.

Singh, Rajeshwar

Shaw, Chia C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00360a030

The oxidation of the 6-(diacylamino)penicillins is a convenient, high yield route to the penicillin 1α-sulfoxides.The yield of the 1α-sulfoxide is dependent on the solvent, the temperature, the C-3 ester function, and the substituent at the C-2 position.T

Full text of DOI:10.1021/jo00360a030

Products guided by the article

Product name:(2S,5R,6R)-6-(Bis-phenylacetyl-amino)-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid 2,2,2-trichloro-ethyl ester

Cas No:80334-31-2

R&D Labs maybe for 80334-31-2

Guangzhou Reachin Chemical Co., Ltd

Contact:+86-20-37087379 ext.604

Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China
Zhenjiang Haitong Chemical Industry Co., Ltd.

Contact:+86 (511) 8448-0369

Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China
CHENGDU CHENLV HERB CO.,LTD

Contact:+86-28-88523492

Address:714rooms of Time Square, Pujiang County
PharmaResources(Kaiyuan)CO,.Ltd

Contact:+86-21-50720028

Address:No.3, Beihuan Road, Economic Development District, Kaiyuan City, Tieling City, Liaoning Province, China 112300
Yingkou Sanzheng Organic Chemical Co. Ltd.

Contact:+86-417-3638818

Address:25 Gengxinli Village, Daqing Road, Yingkou, Liaoning, China

Relevant to this article

Synthesis of diastereomerically and enantiomerically pure 2,3-disubstituted tetrahydrofurans using a sulfoxonium ylide

Doi:10.1021/ja0469075
(2004)
Stereoselective total synthesis of ent-El-1941-2 and epi-ent-El-1941-2

Doi:10.1021/ol0481479
(2004)
Silylene Rearrangements in the Reactions of Recoiling Silicon Atoms with Trimethylsilane

Doi:10.1021/ja00369a047
(1982)
Synthesis of β-enamino acid and heteroaryl acetic acid derivatives by Pd-catalyzed carbonylation of α-chloroimines and 2-chloromethyl aza-heterocycles

Doi:10.1016/j.tetlet.2016.02.035
(2016)
Photocyclization of 1,2-Diarylethylenes in Primary Amines. A Convenient Method for the Synthesis of Dihydro Aromatic Compounds and a Means of Reducing the Loss of Methyl Groups during the Cyclization of o-Methylstilbenes

Doi:10.1021/jo00346a045
(1982)
Enantio- and Diastereoselectivity in the Periodate Oxidation of Sulfides Catalyzed by Bovine Serum Albumin. 2

Doi:10.1021/jo00356a027
(1986)

Article Doi