Oxidation Studies on β-Lactam Antibiotics. The 6-(Diacylamino)penicillins

DOI: 10.1021/jo00360a030

Source and publish data:

Journal of Organic Chemistry p. 1811 - 1815 (1986)

Update date:2022-08-05

Topics:

Authors:

Micetich, Ronald G.

Singh, Rajeshwar

Shaw, Chia C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00360a030

The oxidation of the 6-(diacylamino)penicillins is a convenient, high yield route to the penicillin 1α-sulfoxides.The yield of the 1α-sulfoxide is dependent on the solvent, the temperature, the C-3 ester function, and the substituent at the C-2 position.T

Full text of DOI:10.1021/jo00360a030

Products guided by the article

Product name:(2S,5R,6R)-6-(Bis-phenylacetyl-amino)-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid 2,2,2-trichloro-ethyl ester

Cas No:80334-31-2

R&D Labs maybe for 80334-31-2

Shaanxi King Stone Enterprise Company Limited

Contact:86-29-88353805,13609285751

Address:.209 Keji Road Hi-Tech industrial Develpment Zone .Xian China
Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
Shanghai AoBo Bio-Pharmaceutical Technology Co., Ltd.

Contact:+86-21-51320130-801, 816

Address:Room 601, No. 1011, Halei Road, Zhangjiang High-Tech Park, Pudong, Shanghai
Fujian Huitian Biological Pharmacy Co., Ltd.

Contact:0086-598-8300831; 8339920

Address:No.46,Taijiang Road,Sanming City,Fujian,China
Changsha Yihai Chemical Technology Co.,ltd

website:http://www.cs-yihai.com/

Contact:0731- 85620465

Address:Room 23005, unit 2, the northern building of Xiangsong international building , NO.259 Shaoshan Road , Changsha , Hunan, China.(mainland)

Relevant to this article

Synthesis of diastereomerically and enantiomerically pure 2,3-disubstituted tetrahydrofurans using a sulfoxonium ylide

Doi:10.1021/ja0469075
(2004)
Stereoselective total synthesis of ent-El-1941-2 and epi-ent-El-1941-2

Doi:10.1021/ol0481479
(2004)
Silylene Rearrangements in the Reactions of Recoiling Silicon Atoms with Trimethylsilane

Doi:10.1021/ja00369a047
(1982)
Synthesis of β-enamino acid and heteroaryl acetic acid derivatives by Pd-catalyzed carbonylation of α-chloroimines and 2-chloromethyl aza-heterocycles

Doi:10.1016/j.tetlet.2016.02.035
(2016)
Photocyclization of 1,2-Diarylethylenes in Primary Amines. A Convenient Method for the Synthesis of Dihydro Aromatic Compounds and a Means of Reducing the Loss of Methyl Groups during the Cyclization of o-Methylstilbenes

Doi:10.1021/jo00346a045
(1982)
Enantio- and Diastereoselectivity in the Periodate Oxidation of Sulfides Catalyzed by Bovine Serum Albumin. 2

Doi:10.1021/jo00356a027
(1986)

Article Doi