Reaction of 2-(Methylseleno)- and 2-(Phenylseleno)benzoic Acids and Their Derivatives with tert-Butyl Hydroperoxide. Neighboring Selenium Participation and Facile Formation of Cyclic Selenuranes and a Selenurane Oxide

DOI: 10.1021/jo00133a008

Source and publish data:

Journal of Organic Chemistry p. 2275 - 2278 (1982)

Update date:2022-09-26

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Authors:

Nakanishi, Waro

Ikeda, Yoshitsugu

Iwamura, Hiizu

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Article abstract of DOI:10.1021/jo00133a008

The reaction of 2-(methylseleno)benzoic acid with 1,1'-carbonyldiimidazole followed by addition of tert-butyl hydroperoxide gave 1,1-dihydro-1-tert-butoxy- and 1-hydroxy-1-methyl-3H-2,1-benzoxaselenol-3-ones (3a and 4a), suggesting the intramolecular inse

Full text of DOI:10.1021/jo00133a008

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Product name:1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one

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