
Journal of the American Chemical Society p. 4233 - 4240 (1982)
Update date:2022-08-03
Topics:
Grieco, Paul A.
Ohfune, Yasufumi
Majetich, George F.
Wang, C. L. J.
A stereocontrolled total synthesis of the sesquiterpene lactone dl-helenalin (2) is described.The synthesis starts with cyclopentenol 3 and proceeds via the intermediacy of perhydroazulenone 20.Elaboration of 20 into epoxy alcohol 28 sets the stage for in
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Doi:10.1002/hlca.19830660508
(1983)Doi:10.1016/S0040-4039(00)86926-9
(1982)Doi:10.1016/S0040-4039(00)86808-2
(1982)Doi:10.1016/0040-4020(82)80005-7
(1982)Doi:10.1007/BF00522127
(1982)Doi:10.1002/anie.202009155
(2020)