CONVERSION OF A DIIRON μ-KETENE COMPLEX, FpCH2COFp (Fp=(η5-C5H5)Fe(CO)2), INTO BINUCLEAR CATIONIC OXYCARBENE COMPLEXES AND THEIR BIMODAL REACTIVITIES.

DOI: 10.1016/0022-328X(87)80437-0

Source and publish data:

Journal of Organometallic Chemistry p. C43 - C46 (1987)

Update date:2022-08-02

Topics:

Authors:

Akita, Munetaka

Kondoh, Atsuo

Kawahara, Takashi

Moro-oka, Yoshihiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(87)80437-0

Reactions of a bimetallic μ-ketene complex, FpCH2COFp, with electrophiles take place at the acyl oxygen atom to give cationic binuclear oxycarbene complexes.Bifunctionality of their cationic enol ether structure permits subsequent transformation both with nucleophiles and electrophiles.

Full text of DOI:10.1016/0022-328X(87)80437-0

Products guided by the article

Product name:{(η5-Cp)iron(carbonyl)2C(OMe)CH2

Cas No:82246-54-6

R&D Labs maybe for 82246-54-6

Suzhou ATL Chemical Co.,ltd

Contact:+86-0512-69209969

Address:Room 317,Lushan Road,Suzhou New District,Jiangsu Province,China.
Hubei Lansun Biochemical Pharmaceutical Co., Ltd

Contact:714-6395977

Address:No. 81 Pengcheng Avenue, economic and technological development zone, Huangshi City, Hubei Province,China
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD

Contact:86-21-60560171

Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
Tianjin Chemsyntech Chemical Co., Ltd

Contact:+86-22-60872258

Address:Haitai green industry base in Tianjin, K1,5-601
Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China

Relevant to this article

A new polycyclic system containing the 1,4-benzodiazepine and isoindolinone fragments: Synthesis and structure

Doi:10.1007/s11172-011-0258-9
(2011)
Annelative Ring Expansion via Intramolecular <2 + 2> Photocycloaddition of α,β-Unsaturated γ-Lactones and Reductive Cleavage: Synthesis of Hydrocyclopentacyclooctene-5-carboxylates

Doi:10.1021/jo00140a001
(1982)
Nitriles in organic synthesis: Synthesis of some new 2-heterocyclic benzothiazole derivatives

Doi:10.1080/10426500701323432
(2007)
Cation-induced crown porphyrin dimers of oxovanadium(IV)

Doi:10.1021/ic00140a006
(1982)
Doi:10.1016/S0020-1693(00)90331-1
(1982)
Doi:10.1002/jps.2600661209
(1977)

Article Doi