CONVERSION OF A DIIRON μ-KETENE COMPLEX, FpCH2COFp (Fp=(η5-C5H5)Fe(CO)2), INTO BINUCLEAR CATIONIC OXYCARBENE COMPLEXES AND THEIR BIMODAL REACTIVITIES.

DOI: 10.1016/0022-328X(87)80437-0

Source and publish data:

Journal of Organometallic Chemistry p. C43 - C46 (1987)

Update date:2022-08-02

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Authors:

Akita, Munetaka

Kondoh, Atsuo

Kawahara, Takashi

Moro-oka, Yoshihiko

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Article abstract of DOI:10.1016/0022-328X(87)80437-0

Reactions of a bimetallic μ-ketene complex, FpCH2COFp, with electrophiles take place at the acyl oxygen atom to give cationic binuclear oxycarbene complexes.Bifunctionality of their cationic enol ether structure permits subsequent transformation both with nucleophiles and electrophiles.

Full text of DOI:10.1016/0022-328X(87)80437-0

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