CONVERSION OF A DIIRON μ-KETENE COMPLEX, FpCH2COFp (Fp=(η5-C5H5)Fe(CO)2), INTO BINUCLEAR CATIONIC OXYCARBENE COMPLEXES AND THEIR BIMODAL REACTIVITIES.

DOI: 10.1016/0022-328X(87)80437-0

Source and publish data:

Journal of Organometallic Chemistry p. C43 - C46 (1987)

Update date:2022-08-02

Topics:

Authors:

Akita, Munetaka

Kondoh, Atsuo

Kawahara, Takashi

Moro-oka, Yoshihiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(87)80437-0

Reactions of a bimetallic μ-ketene complex, FpCH2COFp, with electrophiles take place at the acyl oxygen atom to give cationic binuclear oxycarbene complexes.Bifunctionality of their cationic enol ether structure permits subsequent transformation both with nucleophiles and electrophiles.

Full text of DOI:10.1016/0022-328X(87)80437-0

Products guided by the article

Product name:{(η5-Cp)iron(carbonyl)2C(OMe)CH2

Cas No:82246-54-6

R&D Labs maybe for 82246-54-6

Shaanxi Lighte Optoelectronics Material Co., Ltd.

Contact:+86-29-88320728-622/619/620

Address:No.55 INDUSTRY ROAD 2,XI'AN NATIONAL CIVIL AEROSPACE INDUSTRIAL PARK.XI'AN China 710065.
Taizhou Sunny Chemical Co.,Ltd

Contact:+86-523-86920899 +86-13951172783

Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China
Fuxin Jintelai Fluorin Chemical Co., Ltd.

Contact:+86-0418-8229599

Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China
Hubei Danao Pharmaceutical Co.,Ltd.

website:http://www.danaopharm.com

Contact:+86-719-5251167

Address:Fandan Road,Danjiangkou,Hubei
Shanghai Zhihua ChemTech Co., Ltd.

Contact:+86-13774313779

Address:Room 817 Suite B 3333 Shenjiang Road

Relevant to this article

A new polycyclic system containing the 1,4-benzodiazepine and isoindolinone fragments: Synthesis and structure

Doi:10.1007/s11172-011-0258-9
(2011)
Annelative Ring Expansion via Intramolecular <2 + 2> Photocycloaddition of α,β-Unsaturated γ-Lactones and Reductive Cleavage: Synthesis of Hydrocyclopentacyclooctene-5-carboxylates

Doi:10.1021/jo00140a001
(1982)
Nitriles in organic synthesis: Synthesis of some new 2-heterocyclic benzothiazole derivatives

Doi:10.1080/10426500701323432
(2007)
Cation-induced crown porphyrin dimers of oxovanadium(IV)

Doi:10.1021/ic00140a006
(1982)
Doi:10.1016/S0020-1693(00)90331-1
(1982)
Doi:10.1002/jps.2600661209
(1977)

Article Doi