{(η5-Cp)iron(carbonyl)2C(OMe)CH2

Base Information

Chemical Name:{(η5-Cp)iron(carbonyl)2C(OMe)CH2
CAS No.:82246-54-6
Molecular Formula:C₁₀H₁₀FeO₃
Molecular Weight:234.035
Hs Code.:

Synonyms:{(η5-Cp)iron(carbonyl)2C(OMe)CH2

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Chemical Property of {(η5-Cp)iron(carbonyl)2C(OMe)CH2

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Technology Process of {(η5-Cp)iron(carbonyl)2C(OMe)CH2

There total 2 articles about {(η5-Cp)iron(carbonyl)2C(OMe)CH2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 111582-10-6
{(η5-Cp)iron(carbonyl)2CH2C(OMe)(carbonyl)2iron(η5-Cp)}(TfO)

: 38117-54-3
cyclopentadienyl iron(II) dicarbonyl dimer

: 82246-54-6
{(η5-Cp)iron(carbonyl)2C(OMe)CH2

Guidance literature:: With methanol; sodium methylate; In methanol; dichloromethane; Addn. of NaOMe in MeOH to CH2Cl2 soln. of FpCH2C(OMe)FpTfO (Ar, -78°C).; Removal of solvent at room temp., extn. with hexane, (1)H NMR.;

Reference yield:

: 111582-10-6
{(η5-Cp)iron(carbonyl)2CH2C(OMe)(carbonyl)2iron(η5-Cp)}(TfO)

: 90858-61-0
{(η5-Cp)iron(carbonyl)2(PPh3)}CF3SO3

: 82246-54-6
{(η5-Cp)iron(carbonyl)2C(OMe)CH2

Guidance literature:: With triphenylphosphine; In dichloromethane; Dissolution of FpCH2C(OCH3)FpTfO and PPh3 in CH2Cl2 (Ar), yellow homogeneous soln. is obtained.; Evapn. of residue. Addn. of ether to acetone soln. of residue pptd. Fp(PPh3)TfO.;

Reference yield: 11.0%

: 82246-54-6
{(η5-Cp)iron(carbonyl)2C(OMe)CH2

: 98-88-4
benzoyl chloride

: (C₅H₅)(CO)Fe(CH₂C(OCH₃)C(OC(O)C₆H₅)CH₃)

Guidance literature:: With methyllithium; In tetrahydrofuran; soln. of MeLi added to a soln. of Fe-compd. at -78°C, warmed to 10°C over 1.75 h, cooled to -78°C, PhC(O)Cl added; warmed to room temp., evapd., extd. with toluene, chromy. on alumina with ether/hexane;
DOI:10.1016/0022-328X(86)80501-0