Alkylation and Acylation of Co-ordinated Tertiary Phosphines: the Nucleophilic Substitution of the Carbanions derived from 4(Ph2PCH2PPh2)> (M = Cr, Mo, or W)

DOI: 10.1039/c39820000286

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 286 - 287 (1982)

Update date:2022-07-30

Topics:

Authors:

Al-Jibori, Subhi

Shaw, Bernard L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39820000286

Complexes of the type are readily deprotonated by strong bases and the resultant carbanions attacked by nucleophiles such as MeI, EtI, CH2:CHCH2Cl, PhCH2Cl, Me3SiCl, Ph2PCl, PhCOCl, or MeC6H4COCl, to effect C-substitution.

Full text of DOI:10.1039/c39820000286

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Mo(CO)4(P(C₆H₅)2CH(COC₆H₅)P(C₆H₅)2)

Cas No:82328-14-1

R&D Labs maybe for 82328-14-1

Zhangjiagang Jianing Import & Export Co.,Ltd.

Contact:086-512-55379012 13913607595

Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
Hangzhou Hysen Pharma co.,Ltd.

website:http://www.hysenpharma.cn/

Contact:0086-571-88298791

Address:#701,Gudun Road Hangzhou
Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
Yingkou Sanzheng New Technology Chemical Industry Co., Ltd.

Contact:+86-417-2927806

Address:yingkou
Hunan Shineway Enterprise Co., Ltd.

Contact:+86-731-86303875

Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China

Relevant to this article

Organotransition-metal complexes of multidentate ligands XV. Chelate-assisted synthesis of molybdenum(II) carbonyl complexes; crystal structure of 2-dppm)(η¹-dppm)(CO)2Br2> (dppm = bis(diphenylphosphino)methane)

Doi:10.1016/0022-328X(91)86099-C
(1991)
ELECTROCHEMICAL HYDROXYSELENENYLATION AS A NEW METHOD FOR ONE-STEP PREPARATION OF α-ARYLSELENO-α,β-UNSATURATED ALDEHYDES FROM 3-HYDROXYALKYNES

Doi:10.1016/S0040-4039(00)87049-5
(1982)
Systematic CO dissociation kinetics of (μ₂-H)(H)Os₃(CO)₁₀L clusters (L=P-donor ligands)

Doi:10.1016/s0020-1693(97)05466-2
(1997)
THIOPHENOL ADDITIONS TO ALKENYLIDENECYCLOPROPANES. A NOVEL SYNTHESIS OF KARAHANAENONE

Doi:10.1016/S0040-4039(00)87118-X
(1982)
Thionation of N-(ω-halogenoalkyl)-substituted amides with Lawesson's reagent: Facile synthesis of 4,5-dihydro-1,3-thiazoles and 5,6-dihydro-4H-1,3- thiazines

Doi:10.1002/hlca.200590000
(2005)
Chemoselective Desilylation of Silyl Enol Ethers with Tributyltin Fluoride Catalyzed by Palladium

Doi:10.1021/ja00355a037
(1983)

Article Doi