Alkylation and Acylation of Co-ordinated Tertiary Phosphines: the Nucleophilic Substitution of the Carbanions derived from 4(Ph2PCH2PPh2)> (M = Cr, Mo, or W)

DOI: 10.1039/c39820000286

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 286 - 287 (1982)

Update date:2022-07-30

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Authors:

Al-Jibori, Subhi

Shaw, Bernard L.

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Article abstract of DOI:10.1039/c39820000286

Complexes of the type are readily deprotonated by strong bases and the resultant carbanions attacked by nucleophiles such as MeI, EtI, CH2:CHCH2Cl, PhCH2Cl, Me3SiCl, Ph2PCl, PhCOCl, or MeC6H4COCl, to effect C-substitution.

Full text of DOI:10.1039/c39820000286

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