Canadian Journal of Chemistry p. 1098 - 1100 (1982)
Update date:2022-08-03
Topics:
Shahidi, Fereidoon
Tidwell, Thomas T.
Reaction of 1,2-dimethyl-1,2-dihydrophthalic anhydride (8) with t-BuOONa at 40 deg C gave o-xylene as the only observed product.This reaction is proposed to occur through intermediacy of the anionic peroxide 10 whose conversion to o-xylene is calculated to be exothermic by 84 kcal/mol.Extension of this reaction to systems that do not have the possibility for gaining aromatic stabilization was unsuccessful.
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