, EIN IN CH2Cl2-LOESUNG DREIFACH KOORDINIERTER KATIONISCHER PLATIN(II)-KOMPLEX

DOI: 10.1016/S0022-328X(00)84334-X

Source and publish data:

Journal of Organometallic Chemistry p. C61 - C65 (1982)

Update date:2022-08-02

Topics:

Authors:

Scherer, O. J.

Jungmann, H.

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Article abstract of DOI:10.1016/S0022-328X(00)84334-X

The interaction of cis-<(Ph3PCH2)(Ph3P)PtCl2> with aluminium(III) chloride in CH2Cl2 affords the three coordinate cationic platinum(II) complex <(Ph3PCH2)(Ph3P)PtCl> which is a useful starting material for platinum complexes with four different ligands.With Ph3As and Me2S the cationic phosphorus ylide complexes <(Ph3PCH2)(Ph3P)(Ph3As)PtCl> and <(Ph3PCH2)(Ph3P)(Me2S)PtCl> are formed.

Full text of DOI:10.1016/S0022-328X(00)84334-X

Products guided by the article

Product name:[((C₆H₅)3PCH₂)((C₆H₅)3P)(CH₃CN)PtCl]⁽¹⁺⁾*[AlCl₄]^(1-)=[((C₆H₅)3PCH₂)((C₆H₅)3P)(CH₃CN)PtCl][AlCl₄]

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