Journal of Organometallic Chemistry p. 191 - 204 (1982)
Update date:2022-08-02
Topics:
Sicker, Ulrich
Meller, Anton
Maringgele, Walter
A series of monomeric carbiminoboranes is obtained by treatment of isonitriles with organolithium compounds and subsequent treatment with aminohaloboranes. .By an analogous reaction carbiminosilanes can be prepared, having a hydrogen atom in α-position to the imine group.Carbiminosilanes react with aminohaloboranes to give trimethylsilylenaminoboranes and in the case of 1-methyl-5-phenyl-2-trimethylsilyl-2-imidazoline cleavage of the Si-C bond occurs.The compounds are characterized analytically and spectroscopic ally (IR; NMR; 1H, 11B, 29Si; MS).
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Doi:10.1002/hlca.19820650210
(1982)Doi:10.1016/0040-4020(82)85116-8
(1982)Doi:10.1055/s-1982-29885
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(1984)Doi:10.1248/cpb.30.2641
(1982)
