THE REGIOSELECTIVITY OF THE REDUCTIVE RING-CLEAVAGE OF THE ACETAL RING OF 4,6-O-BENZYLIDENEHEXOPYRANOSIDES

DOI: 10.1016/S0008-6215(00)82220-X

Source and publish data:

Carbohydrate Research p. 55 - 68 (1982)

Update date:2022-08-03

Topics: Regioselectivity

Authors:

Fuegedi, Peter

Liptak, Andras

Nanasi, Pal

Szejtli, Jozsef

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Article abstract of DOI:10.1016/S0008-6215(00)82220-X

The hydrogenolytic ring-cleavage of benzyl 4,6-O-benzylidene-β-D-glucopyranoside derivatives with LiAlH₄-AlCl₃ was investigated in relation to the bulk of the C-3 substituens (H, OMe, OEt, OPr, OBzl).In ether-dichloromethane (2:1), 4

Full text of DOI:10.1016/S0008-6215(00)82220-X

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